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Modified Parsons-Lee theory for fluids of linear fused hard sphere chains

 

作者: SZABOLCS VARGA,   ISTVÁN SZALAI,  

 

期刊: Molecular Physics  (Taylor Available online 2000)
卷期: Volume 98, issue 10  

页码: 693-698

 

ISSN:0026-8976

 

年代: 2000

 

DOI:10.1080/00268970009483337

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The Parsons-Lee theory has been modified to study the liquid-crystalline phase behaviour of the linear fused hard sphere chain fluids. The modification of the Parsons-Lee theory is based on the application of the so-called effective molecular volume instead of the real molecular volume. This alteration does not mean any change for the Parsons-Lee treatment of the hard convex bodies but does for the non-convex ones. The results of the modified Parsons-Lee theory show very good agreement with simulations not only for the location of the isotropic-nematic phase transition but for the equation of state.

 

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