Modified Parsons-Lee theory for fluids of linear fused hard sphere chains
作者:
SZABOLCS VARGA,
ISTVÁN SZALAI,
期刊:
Molecular Physics
(Taylor Available online 2000)
卷期:
Volume 98,
issue 10
页码: 693-698
ISSN:0026-8976
年代: 2000
DOI:10.1080/00268970009483337
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The Parsons-Lee theory has been modified to study the liquid-crystalline phase behaviour of the linear fused hard sphere chain fluids. The modification of the Parsons-Lee theory is based on the application of the so-called effective molecular volume instead of the real molecular volume. This alteration does not mean any change for the Parsons-Lee treatment of the hard convex bodies but does for the non-convex ones. The results of the modified Parsons-Lee theory show very good agreement with simulations not only for the location of the isotropic-nematic phase transition but for the equation of state.
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