Faceting of a Ge(111) surface and its vicinals during Ag adsorption
作者:
E. Suliga,
M. Henzler,
期刊:
Journal of Vacuum Science&Technology A: Vacuum, Surfaces, and Films
(AIP Available online 1983)
卷期:
Volume 1,
issue 3
页码: 1507-1511
ISSN:0734-2101
年代: 1983
DOI:10.1116/1.572176
出版商: American Vacuum Society
关键词: germanium;silver;high temperature;surface energy;monolayers;metallization;coatings;electron diffraction;stability;adsorption;sorptive properties;crystal structure
数据来源: AIP
摘要:
The stability of a Ge(111) surface and its vicinals were studied by LEED for clean and Ag covered conditions. Before deposition the surfaces were macroscopically smooth. After deposition of only a few tenths of a monolayer of Ag and heating to 400 °C, the surface consisted of narrow (544) facet planes and wide (111) terraces. At coverage above 0.7 the (544) facets disappeared and (211) facets started growing. The facets had dimensions in the range of 10 μ, so that they could be observed with an optical microscope. Furthermore, a rotation of ledges into directions with low indices was observed. The results show that the equilibrium shape of a surface is drastically changed by a coverage of a fraction of a monolayer due to the formation of new minima of the surface free energy at peculiar high index vicinal surfaces.
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