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New highTcsuperconductor: (In,Pb,Cu)Sr2(Ca,Y)Cu2O7−&dgr;

 

作者: R. S. Liu,   S. F. Hu,   P. P. Edwards,  

 

期刊: Applied Physics Letters  (AIP Available online 1991)
卷期: Volume 59, issue 8  

页码: 985-987

 

ISSN:0003-6951

 

年代: 1991

 

DOI:10.1063/1.106322

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Bulk superconductivity was observed in the new system (InxPb0.75−xCu0.25)Sr2(Ca0.5Y0.5)Cu2O7−&dgr;. An increase in indium doping, 0≤x≤0.2, into the Pb sites results in an increase in the superconducting transition temperatureTcfrom 45 K forx=0 to 60 K forx=0.2. For nominal compositionsx≳0.2, a decrease inTcwas observed, and an increase in the concentration of an impurity phase. From the results of the x‐ray diffraction and energy‐ dispersive spectrometry, we identify the phase responsible for the superconductivity to be [In0.06(1)Pb0.69(1)Cu0.25]Sr1.99(7)[Ca0.47(1)Y0.53(2)]Cu2O7−&dgr;; this phase resulted from the synthesis of a sample of nominal composition (In0.2Pb0.55Cu0.25)Sr2(Ca0.5Y0.5)Cu2O7−&dgr;.

 

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