Deintercalation Process of Fluorinated Carbon Fibres. Part I - Controlled Rate Evolved Gas Analysis
作者:
F. Moguet,
S. Bordere,
L. Rabardel,
A. Tressaud,
F. Rouquerol,
P. Llewelly,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 310,
issue 1
页码: 111-118
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808045323
出版商: Taylor & Francis Group
关键词: carbon fibres;fluorine intercalation;deintercalation;controlled transformation rate thermal analysis;mass spectrometry
数据来源: Taylor
摘要:
The intercalation of fluorine into graphite leads to graphite intercalation compounds (F-GICs) exhibiting potential properties such as the storage and transport of fluorine. Stage-1 compounds with C2.5F to C4F compositions are obtained by fluorination treatments at room temperature of ex-pitch, high-temperature treated carbon fibres under 10 bars F2pressure in the presence of gaseous HF. The deintercalation process of fluorine species has been studied by evolved gas analysis: the F-GICs are decomposed using the Controlled transformation Rate Thermal Analysis (CRTA) method. The thermal analysis curve obtained for stage-1 F-GICs exhibits three decomposition steps. The first two steps correspond to a simultaneous deintercalation of atomic fluorine F and gaseous HF and the third step (above 460°C) to the degradation of the compound with formation of C2F4and CF4which further dissociate in the spectrometer to CFn(1 ≤ n ≤ 3) species.
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