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Synthesis of enantiomerically pure tricarbonylchromium(0) complexes oforthosubstituted styrenes from(S)‐α‐Methylbenzylamine

 

作者: Paul W. N. Christian,   Susan E. Gibson,   Richard Gil,   P. Caroline V. Jones,   Carlos F. Marcos,   Frank Prechtl,   Adam T. Wierzchleyski,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  （WILEY Available online 1995）
卷期: Volume 114, issue 4‐5  

页码: 195-202

 

ISSN:0165-0513

 

年代: 1995

 

DOI:10.1002/recl.19951140411

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractTricarbonylchromium(0) complexes of sulfur, phosphorus, silicon, iodine, tin and carbon substituted(S)‐(α‐methylbenzyl)dimethylamines are oxidized by dimethyldioxirane to enantiomerically pure tricarbonylchromium(0) complexes of substituted styrenes; the reactions proceed via a chemoselective oxidation of the tertiary amines to theirN‐oxides, one of which was isolated, and a subsequent Cope re

 

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