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A multi‐mode approach to finite, three‐dimensional, nonlinear viscoelastic behavior of polymer glasses

 

作者: T. A. Tervoort,   E. T. J. Klompen,   L. E. Govaert,  

 

期刊: Journal of Rheology  (AIP Available online 1996)
卷期: Volume 40, issue 5  

页码: 779-797

 

ISSN:0148-6055

 

年代: 1996

 

DOI:10.1122/1.550755

 

出版商: The Society of Rheology

 

关键词: Glass, polymer;Yield;Viscoelasticity, nonlinear solid;Solid‐phase rheology;Plastic deformation;GLASS;POLYMERS;YIELD STRENGTH;PLASTICITY;RELAXATION TIME;STRESS RELAXATION;STRAIN RATE

 

数据来源: AIP

 

摘要:

In this study a phenomenological constitutive model is proposed to describe the finite, nonlinear, viscoelastic behavior of glassy polymers up to the yield point. It is assumed that the deformation behavior of a glassy polymer up to the yield point is completely determined by the linear relaxation time spectrum and that the nonlinear effect of stress is to alter the intrinsic time scale of the material. A quantitative three‐dimensional constitutive equation for polycarbonate as a model polymer was obtained by approximating the linear relaxation time spectrum by eighteen Leonov modes, all exhibiting the same stress dependence. A single Leonov mode is a Maxwell model employing a relaxation time that is dependent on an equivalent stress proportional to the Von Mises stress. Furthermore, a Leonov mode separates the (elastic) hydrostatic and (viscoelastic) deviatoric stress response and accounts for the geometrical complexities associated with simultaneous elastic and plastic deformation. Using a single set of parameters, the multi‐mode Leonov model is capable of describing realistic constant strain rate experiments, including the strain rate dependent yield behavior. It is also capable of giving a quantitative description of nonlinear stress‐relaxation experiments.

 

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