The Interrelation Between the Microphase Structure of Sequential Interpenetrating Polymer Networks and the Crosslinking Density of Penetrating Networks
作者:
V.V. Shilov,
S.Yu. Lipatov,
Yu.P. Gomza,
E.I. Oranskaya,
V.F. Matyushov,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1990)
卷期:
Volume 27,
issue 4
页码: 459-477
ISSN:0022-233X
年代: 1990
DOI:10.1080/00222339009349569
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The microphase structure of single polyurethane (PU) and acrylate networks as well as sequential interpenetrating polymer networks (IPNs), produced by the forming of a PU network in the presence of monomers of a penetrating network, was studied by small- and wide-angle x-ray analysis. It was established that each network component was of a two-phase structure consisting of disordered phase-separated microregions. the higher crosslink density of the acrylate network results in its higher heterogeneity. in IPNs, phase separation of a complex nature is realized: the PU matrix preserves some features of a single network structure, and the second component forms microregions 5-10 nm in size while retaining a certain level of interpenetra-tion of both network components. the microphase structure parameters of such systems are greatly dependent on the crosslink density of the penetrating network. This suggests the influence of a three-dimensional network of chemical bonds on the interdiffusion of branched fragments of the penetrating network and molecular chains of the matrix, one leading to the retardation of phase separation.
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