Thermotropic Mesophases of Benzene Derivatives with Terminally Hydroxylated Groups
作者:
Naomi Hoshino,
Hiroshi Takahashi,
Yoshio Matsunaga,
Hiroshi Okamoto,
Tadaoki Mitani,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 216,
issue 1
页码: 265-268
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208028784
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Nine benzene derivatives substituted with at least one long alkyl chain in common and with various terminally hydroxylated groups have been prepared. Thermotropic meso-phases were observed in seven compounds and the hydrogen bonding of the alcoholic OH groups seems to be responsible for this behavior of novel one-ring mesogens. The X-ray diffraction patterns are consistent with a common structural model involving bimolecular layers of hydrogen bonding network separated by fully interdigitated alkyl chains.
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