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A new approach to the synthesis of 1, 6‐anhydro‐2‐azido‐2‐deoxy‐β‐D‐glucopyranose derivatives

 

作者: M. Kloosterman,   M. P. de Nijs,   J. H. van Boom,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  (WILEY Available online 1984)
卷期: Volume 103, issue 7‐8  

页码: 243-244

 

ISSN:0165-0513

 

年代: 1984

 

DOI:10.1002/recl.19841030706

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

Abstract1, 6‐Anhydro‐β‐D‐mannopyranose was converted in three steps into 1, 6‐anhydro‐3‐0‐(4‐methoxybenzoyl)‐4‐0‐allyl‐β‐D‐mannopyranose in high overall yield. Treatment of the latter with trifluoromethanesulphonic anhydride, followed by direct displacement at 20°c of the triflate ester with lithium azide afforded almost quantitatively 1, 6‐anhydro‐2‐azido‐2‐deoxy‐3‐0

 

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