A New interpretation ofMc, the critical molar mass for chain entanglement
作者:
Renyuan Qian,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1999)
卷期:
Volume 38,
issue 1-2
页码: 75-77
ISSN:0022-2348
年代: 1999
DOI:10.1080/00222349908248106
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A new interpretation ofMc, the critical molar mass for chain entanglement in polymers, is presented from the viewpoint of chain interpenetration in the melt. It is shown that, atM=Mc, the number of chains in the melt connected by chain interpenetration reaches approximately 10 being independent of chemical structure of the chain. This work also interprets the empirical rule of van Krevelen. Arguments are presented for the theory that the majority of the chain entanglements are not topological in nature, but rather a local interaction of cohesive nature.
点击下载:
PDF (180KB)
返 回