Twin screw extruders as polymerization reactors for a free radical homo polymerization
作者:
K. J. Ganzeveld,
L.P. B. M. Janssen,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1993)
卷期:
Volume 71,
issue 3
页码: 411-418
ISSN:0008-4034
年代: 1993
DOI:10.1002/cjce.5450710310
出版商: Wiley Subscription Services, Inc., A Wiley Company
关键词: extruder;polymerization reactor;methacrylates;free radical polymerization
数据来源: WILEY
摘要:
AbstractThe bulk polymerization ofn‐butylmethacrylate was investigated in a counter‐rotating twin screw extruder. It appeared that the gel effect, occurring with bulk polymerizations, affected the polymerization progress very strongly. Due to this effect the conversion of the reaction is independent of the rotation speed of the screws. The reactive extrusion diagram, presented in this paper, indicates how the different phenomena interact with each other and helps to understand the influences of extruder parameters and reaction parameters on the proc
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