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Excess electrons in molten salts

 

作者: G. Malescio,  

 

期刊: Molecular Physics  (Taylor Available online 1990)
卷期: Volume 69, issue 5  

页码: 895-901

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000100671

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The polaron theory of electrons solvated in molten salts is applied to dilute solutions of Cs in molten CsI. Structural and thermodynamic properties of the excess electron and of the surrounding liquid are calculated as well as the electronic absorption spectrum which is compared with the result of optical studies. The influence of the electron-cation attraction on the electron localization is discussed within the model considered.

 

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