The copolymerization of unsaturated carboxylic acids with styrene and an unsaturated tertiary amine in benzene
作者:
František Harbák,
Milan Bezděk,
Vlasta Hynková,
Jarmila Svobodová,
期刊:
Die Makromolekulare Chemie
(WILEY Available online 1982)
卷期:
Volume 183,
issue 11
页码: 2675-2684
ISSN:0025-116X
年代: 1982
DOI:10.1002/macp.1982.021831106
出版商: Hüthig&Wepf Verlag
数据来源: WILEY
摘要:
AbstractThe copolymerization parameters of 2‐acryloyoxybenzoic (AOB) and 2‐methacryloyloxybenzoic (MOB) acids, methyl 2‐methacryloyloxybenzoate (MMOB), andN‐methyl‐N‐phenyl‐2‐aminoethyl methacrylate (MPAM) with styrene in benzene solution were determined and used in the calculation of the Alfrey‐Price copolymerization constantseandQfor AOB, MOB, MMOB, and MPAM. UsingeQthus determined and the corresponding tabulated values for methacrylic acid (MAA), the copolymerization parameters of pairs AOB‐MPAM, MOB‐MPAM, MMOB‐MPAM, and MAA‐MPAM were calculated. They are compared with those determined by the copolymerization of these pairs in which the interaction of functional groups o
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