Radiation-induced changes in physical properties of bulk polyethylene. I. Effect of crystallization conditions
作者:
H. Jenkins,
A. Keller,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1975)
卷期:
Volume 11,
issue 3
页码: 301-323
ISSN:0022-2348
年代: 1975
DOI:10.1080/00222347508018913
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Melt crystallized polyethylenes with different crystallization histories were irradiated with γ-rays and examined for various properties. These include solubility (gel content), melting and recrystallization behavior, load extension behavior, and creep properties. Even for the same dose, very significant differences were observed for the different sample types. Although such differences have been reported previously, the present work reveals that these differences can be unusually large and that they are displayed by a range of different tests with a consistent correlation between them. The underlying trend is that in poorly crystallized samples the radiation is much more effective in forming networks than in samples of highly developed crystallinity. This finding may merely indicate that cross-linking is more abundant in the amorphous region than in the crystallites; nevertheless, analogy with single crystals suggests that in addition details of the fold surface morphology and the nature of the lamellar contact may also have a part to play. Among other properties, the elasticity of cross-linked melt was analyzed and found to be consistent with simple rubber elasticity theory, leading to an estimate of both the number of effective cross-links and of intrinsic entanglements acting as cross-links. The most conspicuous effects were observed in the creep behavior where different sample types irradiated to the same dose could behave as viscous liquids and true rubbers according to crystallization history. The relevance of such findings for the technological irradiation of polyethylene should be self-evident, particularly as the doses involved were those commonly employed in industrial applications.
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