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Destruction of hazardous air pollutants using a fast rise time pulsed corona reactor

 

作者: R. A. Korzekwa,   M. G. Grothaus,   R. K. Hutcherson,   R. A. Roush,   R. Brown,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1998)
卷期: Volume 69, issue 4  

页码: 1886-1892

 

ISSN:0034-6748

 

年代: 1998

 

DOI:10.1063/1.1148859

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Increasingly stringent environmental regulation imposed on both the military and civilian sectors has created a growing demand for alternative abatement methods for a variety of hazardous compounds. One alternative, the nonthermal plasma, shows promise of providing an efficient means for the destruction of dilute concentrations of hazardous air pollutants. The Dahlgren Laboratory of the Naval Surface Warfare Center has extensively investigated one type of nonthermal plasma discharge, the pulsed corona reactor, for the destruction of volatile organic compounds and chemical warfare agents. In this reactor, a fast rise time(∼10 ns),short duration(<100 ns),high-voltage pulse is repetitively delivered to a wire-cylinder electrode geometry, thereby producing a multitude of streamer discharges along its length. The resulting nonthermal plasma contains highly reactive chemical radicals which can interact with and destroy the hazardous molecules entrained in the ambient atmosphere flowing through the reactor volume. Increased electrical efficiency was obtained using a combination of high efficiency constant-current capacitor-charging, high repetition-rate spark gap switching, and resonant energy transfer to the reactor. Promising results have been obtained for toluene, methylene chloride, and dichlorodifluoromethane in air at concentrations of a few hundred parts per million. The device has been operated at voltages up to 30 kV, pulse repetition rates up to 1.4 kHz, and flow rates up to 60l/min. Detailed electrical measurements have been made to properly characterize the electrical properties of the pulsed corona reactor and to validate subsequent improvements in the reactor energy efficiency. ©1998 American Institute of Physics.

 

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