Superlattice ordering in the low-temperature icosahedral phase of Al-Pd-Mn
作者:
T. Ishimasa,
期刊:
Philosophical Magazine Letters
(Taylor Available online 1995)
卷期:
Volume 71,
issue 1
页码: 65-73
ISSN:0950-0839
年代: 1995
DOI:10.1080/09500839508240515
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The low-temperature icosahedral phase, which forms below approximately 700°C near the alloy composition Al71Pd21Mn8has been investigated by means of electron diffraction. Precise analysis of diffraction patterns indicates that the Bravais lattice of the low-temperature phase isPtype, different from the formerly proposedFtype. The six-dimensional lattice parameter of this newP-type lattice is determined to beaP= 20.881 Å by powder X-ray diffraction and is related to the high-temperatureF-type iscosahedral phase byaP= τaF, where τ andaFdenote the golden mean and the six-dimensional lattice parameter respectively of the high-temperature phase. The low-temperature transformation can be understood by a small breaking ofFsymmetry caused by superlattice ordering. A model of the required configuration of atomic surfaces (acceptance regions) is discussed by using the six-dimensional ‘diamond’ lattice. This diamond lattice has a lattice parameteraF2= 2aFand is related to the aboveP-lattice by a scaling transformation.
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