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Superlattice ordering in the low-temperature icosahedral phase of Al-Pd-Mn

 

作者: T. Ishimasa,  

 

期刊: Philosophical Magazine Letters  (Taylor Available online 1995)
卷期: Volume 71, issue 1  

页码: 65-73

 

ISSN:0950-0839

 

年代: 1995

 

DOI:10.1080/09500839508240515

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The low-temperature icosahedral phase, which forms below approximately 700°C near the alloy composition Al71Pd21Mn8has been investigated by means of electron diffraction. Precise analysis of diffraction patterns indicates that the Bravais lattice of the low-temperature phase isPtype, different from the formerly proposedFtype. The six-dimensional lattice parameter of this newP-type lattice is determined to beaP= 20.881 Å by powder X-ray diffraction and is related to the high-temperatureF-type iscosahedral phase byaP= τaF, where τ andaFdenote the golden mean and the six-dimensional lattice parameter respectively of the high-temperature phase. The low-temperature transformation can be understood by a small breaking ofFsymmetry caused by superlattice ordering. A model of the required configuration of atomic surfaces (acceptance regions) is discussed by using the six-dimensional ‘diamond’ lattice. This diamond lattice has a lattice parameteraF2= 2aFand is related to the aboveP-lattice by a scaling transformation.

 

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