Polymorphism and the crystal structures of InSb at elevated temperature and pressure
作者:
Shu‐Cheng Yu,
Ian L. Spain,
Earl F. Skelton,
期刊:
Journal of Applied Physics
(AIP Available online 1978)
卷期:
Volume 49,
issue 9
页码: 4741-4745
ISSN:0021-8979
年代: 1978
DOI:10.1063/1.325546
出版商: AIP
数据来源: AIP
摘要:
Polycrystalline x‐ray diffraction data are reported for three high‐pressure phases of InSb. InSb‐II patterns are indexed on the basis of a body‐centered tetragonal lattice with unit cell parametersa=5.810 A˚ andc=3.136 A˚ atP∼4.3 GPa andT≳100 °C; a unique space group has not been assigned. Possible space groups and structures have been determined for the other high‐pressure phases. Contrary to published results, InSb‐III is orthorhombic witha=5.712 A˚,b=5.357 A˚,c=3.063 A˚ at 11.5 GPa and room temperature, the space group is eitherPmmmorPmmn, andZ=2. InSb‐IV is also orthorhombic witha=2.919 A˚,b=5.618 A˚, andc=3.066 A˚ atP=4.4 GPa and room temperature; the space group isPmm2, andZ=1. Atomic coordinates and appropriate bond angles are also reported.
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