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Polymorphism and the crystal structures of InSb at elevated temperature and pressure

 

作者: Shu‐Cheng Yu,   Ian L. Spain,   Earl F. Skelton,  

 

期刊: Journal of Applied Physics  (AIP Available online 1978)
卷期: Volume 49, issue 9  

页码: 4741-4745

 

ISSN:0021-8979

 

年代: 1978

 

DOI:10.1063/1.325546

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Polycrystalline x‐ray diffraction data are reported for three high‐pressure phases of InSb. InSb‐II patterns are indexed on the basis of a body‐centered tetragonal lattice with unit cell parametersa=5.810 A˚ andc=3.136 A˚ atP∼4.3 GPa andT≳100 °C; a unique space group has not been assigned. Possible space groups and structures have been determined for the other high‐pressure phases. Contrary to published results, InSb‐III is orthorhombic witha=5.712 A˚,b=5.357 A˚,c=3.063 A˚ at 11.5 GPa and room temperature, the space group is eitherPmmmorPmmn, andZ=2. InSb‐IV is also orthorhombic witha=2.919 A˚,b=5.618 A˚, andc=3.066 A˚ atP=4.4 GPa and room temperature; the space group isPmm2, andZ=1. Atomic coordinates and appropriate bond angles are also reported.

 

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