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Reaction of diethyl acetonedicarboxylate with nitrosyl chloride

 

作者: Richard B. Silverman,  

 

期刊: Journal of Heterocyclic Chemistry  （WILEY Available online 1978）
卷期: Volume 15, issue 8  

页码: 1519-1520

 

ISSN:0022-152X

 

年代: 1978

 

DOI:10.1002/jhet.5570150860

 

出版商: Wiley‐Blackwell

 

数据来源: WILEY

 

摘要:

AbstractThe reaction of diethyl acetonedicarboxylate with greater than two equivalents of nitrosyl chloride or the reaction of diethyl isonitrosoacetonedicarboxylate with one equivalent of nitrosyl chloride gave diethyl 4‐hydroxyisoxazole‐3,5‐dicarboxylate in quantitative yield. Mechanistic possibilities are disc

 

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