An investigation of hydrogen concentration profiles in as‐deposited and annealed chemical vapor deposited SiO2films
作者:
Joseph Z. Xie,
Shyam P. Murarka,
Xin S. Guo,
William A. Lanford,
期刊:
Journal of Vacuum Science&Technology B: Microelectronics Processing and Phenomena
(AIP Available online 1988)
卷期:
Volume 6,
issue 6
页码: 1756-1762
ISSN:0734-211X
年代: 1988
DOI:10.1116/1.584173
出版商: American Vacuum Society
关键词: CHEMICAL VAPOR DEPOSITION;VAPOR DEPOSITED COATINGS;ANNEALING;ELECTRICAL PROPERTIES;NITROGEN 15;MEV RANGE 01−10;VERY HIGH TEMPERATURE;SILICA;SILICON;DOPING PROFILES;IMPURITIES;SiO2
数据来源: AIP
摘要:
Hydrogen concentration depth profiles in as‐deposited and annealed chemical vapor deposited silicon oxide [2% P glass, 8% P glass, tetraethylorthosilicate (TEOS), phosphorous‐doped TEOS and plasma oxide] films were measured using the nuclear reaction profiling technique with a 6.4 MeV15N ion beam. The H2/Ar annealing of 450 °C for 60 min in furnace and the rapid thermal annealing at 1000 °C for 60 s in O2or H2/Ar were carried out. It is found that hydrogen concentration is in the range 1021–1022per cm3in as‐deposited films. Annealing at high temperatures, even in hydrogen containing medium, lowers the hydrogen concentration in all films. The hydrogen concentration gradually increased with time when the films were left in the room environment. The electrical properties of the oxide are found to be related to the presence of hydrogen. The observed correlation between the flatband voltage and the hydrogen concentration is presented and discussed.
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