首页   按字顺浏览 期刊浏览 卷期浏览 Local structure and polarization in Pb containing ferroelectric oxides
Local structure and polarization in Pb containing ferroelectric oxides

 

作者: T. Egami,   W. Dmowski,   M. Akbas,   P. K. Davies,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1998)
卷期: Volume 436, issue 1  

页码: 1-10

 

ISSN:0094-243X

 

年代: 1998

 

DOI:10.1063/1.56286

 

出版商: AIP

 

数据来源: AIP

 

摘要:

While the Pb containing ferroelectric and antiferroelectric oxides show a large variety in crystal structure, the pulsed neutron atomic pair-distribution function (PDF) studies indicate that their local atomic structures are surprisingly similar to each other. In particular the environment of Pb is nearly independent of composition, with Pb being strongly off-centered in thePbO12cluster, resulting in a large local polarization. A new model is proposed to describe the interplay between the Pb polarization and the random local structural fluctuation. This model explains the relaxor ferroelectricity from a general point of view, while other models such as nano-domain space charge model and the random field model were introduced specifically for hetero-valent systems such asPb(Mg1/3Nb2/3)O3(PMN). ©1998 American Institute of Physics.

 

点击下载:  PDF (726KB)



返 回