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Syntheses of Selenothioic and Diselenoic Acid Esters

 

作者: Toshiaki Murai,   Shinzi Kato,  

 

期刊: Sulfur reports  （Taylor Available online 1998）
卷期: Volume 20, issue 3  

页码: 397-418

 

ISSN:0196-1772

 

年代: 1998

 

DOI:10.1080/01961779808047924

 

出版商: Taylor & Francis Group

 

关键词: Diselenoic acid esters;seleno-Claisen rearrangement;selenoketenes;selenothioic acidS-esters;selenothioic acidSe-esters;thioacylating agents

 

数据来源: Taylor

 

摘要:

This review covers synthetic methods of three types of selenium counterparts of dithioic acid esters,e.g.selenothioic acidSe-esters, selenothioic acidS-esters, and diselenoic acid esters. These generally utilize a combination of electrophilic thio- or seleno-acylating agents and nucleophilic organoselenium or -sulfur compounds. Observed trends in the stability of the esters are also discussed.

 

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