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Dispersion of Velocity and Anomalous Absorption of Ultrasonics in Nitrogen

 

作者: Alfred Joseph Zmuda,  

 

期刊: The Journal of the Acoustical Society of America  (AIP Available online 1951)
卷期: Volume 23, issue 4  

页码: 472-477

 

ISSN:0001-4966

 

年代: 1951

 

DOI:10.1121/1.1906789

 

出版商: Acoustical Society of America

 

数据来源: AIP

 

摘要:

By means of the interferometer, the velocity and absorption of ultrasonic waves in nitrogen were measured at the frequency of 2.992 mc/sec, in the pressure range of 2.09 to 76 cm of Hg at a temperature of 29°C. A dispersion of velocity was found ranging from 354.3 meters/sec to 364.4 meters/sec. The ratio αexp/αclassdropped from 1.40 to 1.32, and the corresponding value ofCv/Rdropped from 2.50 to 2.08.Theoretical values for the change in velocity and in the absorption ratio, calculated by applying the equations for the exchange of energy between translational and vibrational degrees of freedom, show good agreement with the observed values. The increase in velocity and the decrease in αexp/αclassis interpreted as due to the slow exchange of energy between the translational and rotational degrees of freedom. The relaxation time for rotation was found to be 1.2×10−9second.

 

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