Synthesis and Spectrokinetic Studies of a Series of 2-Ferrocenyl-2-methyl-[2H]-benzopyranes
作者:
Stéphane Anguille,
Pierre Brun,
Robert Guglielmetti,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 2000)
卷期:
Volume 344,
issue 1
页码: 247-252
ISSN:1058-725X
年代: 2000
DOI:10.1080/10587250008023844
出版商: Taylor & Francis Group
关键词: ferrocenyl benzopyrane;photochromic compounds
数据来源: Taylor
摘要:
The synthesis of a series of 2-ferrocenyl-2-methyl-[2H]-benzopyranes and the results of a spectrokinetic study are presented. A broadening of the absorption band in the visible range and the apparition of a second absorption band is observed as compared with the reference compounds. Furthermore important kinetic modifications are observed. From these results a structure can be proposed for a permanent opened form which is observed in polar protic solvents.
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