Modified Einstein model applied to a KBr crystal to study the thermodynamic properties
作者:
Tai-Hyung Kwon,
期刊:
Philosophical Magazine Letters
(Taylor Available online 1992)
卷期:
Volume 65,
issue 5
页码: 261-266
ISSN:0950-0839
年代: 1992
DOI:10.1080/09500839208207545
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Local dynamics of the lattice is taken into consideration to modify the original Einstein model of lattice dynamics, and the modified Einstein model is tested by evaluating the thermodynamic properties of crystalline KBr. Specifically, the thermal expansion, thermal expansion coefficient and specific heat at constant volume have been evaluated as functions of temperature at atmospheric pressure for crystalline KBr using a realistic potential of the formA1R−9+A2R−6±A3R−1, and normal-mode frequencies obtained from local dynamics of two particles allowed to oscillate in a static potential field due to all the rest of particles, assumed at rest in their mean positions. The temperature dependence of these thermodynamic functions is examined in comparison with the available experimental data, and reasonable agreement is observed.
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