EPR and optical absorption spectra of VO2+ions in calcium oxalate monohydrate single crystals
作者:
K.V. Narasimhulu,
V. Padmavathi,
J.Lakshmana Rao,
Y.N. Naidu,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1997)
卷期:
Volume 143,
issue 2
页码: 193-201
ISSN:1042-0150
年代: 1997
DOI:10.1080/10420159708212959
出版商: Taylor & Francis Group
关键词: EPR;Vanadyl ion;Oxalate salts;Spin-Hamiltonian parameters
数据来源: Taylor
摘要:
Electron paramagnetic resonance (EPR) and Optical absorption spectra of vanadyl ions in calcium oxalate monohydrate single crystals have been studied. EPR spectrum at room temperature exhibits an isotropic octet spectrum. The detailed EPR analysis indicates that vanadyl ions exhibit liquid like behaviour. EPR spectrum has been studied at different temperatures. It is found that at 255 K, the EPR spectrum completely disappears. The optical absorption spectrum exhibits three absorption bands characteristic of vanadyl ions in tetragonal symmetry. From the optical data, the crystal field and tetragonal parameters have been evaluated.
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