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Rotational and Translational Proton Tunneling and Relaxation in Condensed Molecular Systems

 

作者: HansPeter Trommsdorff,   Christian Von Borczyskowski,   Jean-Claude Vial,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1992）
卷期: Volume 218, issue 1  

页码: 283-290

 

ISSN:1058-725X

 

年代: 1992

 

DOI:10.1080/10587259208047055

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Quantum motions of protons in organic crystalline solids are monitored via the optical transitions of suitable dye molecules coupled to the potential governing the proton motion. Tunneling splittings are determined using line-narrowing techniques and the relaxation dynamics is measured on timescales extending from picoseconds to hours. The relevance of these properties for material uses is discussed.

 

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