Liquid Crystal Order in a Highly Restrictive Porous Glass
作者:
GermanoS. Iannacchione,
Sihai Qian,
GregoryP. Crawford,
SandraS. Keast,
MaryE. Neubert,
J.William Doane,
Daniele Finotello,
LindsayM. Steele,
PaulE. Sokol,
Slobodan Zumer,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 262,
issue 1
页码: 13-23
ISSN:1058-725X
年代: 1995
DOI:10.1080/10587259508033508
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The thermodynamic and structural properties of octylcyanobiphenyl (8CB) confined to the highly restrictive and randomly interconnected pores of Vycor glass were studied via AC calorimetry, DSC, and small angle neutron scattering. The weakly first order nematic to isotropic phase transition is absent and replaced by a continuous evolution of local orientational ordering with decreasing temperature. The results are consistent with predictions from a model that treats the host media as a collection of noninteracting pore segments. The continuous smectic-A to nematic phase transition is also absent with no evidence of any smectic ordering. In addition, crystallization is replaced by a glass-like melting transition with indications of another melting transition at much lower temperatures.
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