Optical emission spectroscopy studies of the effects of nitrogen addition on diamond synthesis in a CH4–CO2gas mixture
作者:
Tsao‐Ming Hong,
Sheng‐Hsiung Chen,
Yih‐Song Chiou,
Chia‐Fu Chen,
期刊:
Applied Physics Letters
(AIP Available online 1995)
卷期:
Volume 67,
issue 15
页码: 2149-2151
ISSN:0003-6951
年代: 1995
DOI:10.1063/1.114749
出版商: AIP
数据来源: AIP
摘要:
The influence of nitrogen on the growth of diamond using the gas mixtures of CH4–CO2by microwave plasma chemical vapor deposition was investigated. A clear improvement in the surface morphology and quality of the diamond films indicates the beneficial effect of adding nitrogen to CH4–COgas mixtures. Analysis using Auger electron spectroscopy and secondary ion mass spectroscopy shows very low and uniform levels of nitrogen in the diamond films. Atomic nitrogen plays a dominant role in C/H/O/N plasma chemical vapor deposition processes because of the amount of oxygen atoms increased via the titration reaction of nitrogen atoms (a high‐rate reaction): N+NO→N2+O. This produces a significant influence on diamond synthesis in a CH4–CO2–N2gas mixture. ©1995 American Institute of Physics.
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