Mechanisms of Two-Dimensional Smoldering Propagation Through Packed Fuel Beds
作者:
COLOMBA DI BLASI,
期刊:
Combustion Science and Technology
(Taylor Available online 1995)
卷期:
Volume 106,
issue 1-3
页码: 103-124
ISSN:0010-2202
年代: 1995
DOI:10.1080/00102209508907769
出版商: Taylor & Francis Group
关键词: Smoldering combustion;celiulosic material degradation;modeling
数据来源: Taylor
摘要:
A two-dimensional, unsteady, variable property model of the smoldering combustion of an insulating celiulosic bed, in still air, is presented. Chemical processes account for pyrolytic (endothermic)and oxidative (exothermic) degradation of cellulose to volatiles and char, followed by (exothermic) oxidation of char. Physical processes are described by energy, momentum and mass balances for the highly porous solid. The smoldering wave presents a multi-dimensional structure, affected by oxygen transport to the reaction zone (km) and heat losses from the top (hc) and bottom (hw) surfaces of the bed. In particular, as the mass transport coefficient is increased, not only reaction extent but also reaction selectivity varies, with solid pyrolysis becoming more important than solid oxidation. The dependence of the smoldering process on the chemical pathways has also been studied through variations in the pre-exponential factors of the reaction rates.
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