首页   按字顺浏览 期刊浏览 卷期浏览 The Effect of Molecular Weight and Molecular Weight Distribution on the Non‐Newtonian B...
The Effect of Molecular Weight and Molecular Weight Distribution on the Non‐Newtonian Behavior of Ethylene‐Propylene‐Diene Polymers

 

作者: C. K. Shih,  

 

期刊: Transactions of the Society of Rheology  (AIP Available online 1970)
卷期: Volume 14, issue 1  

页码: 83-114

 

ISSN:0148-6055

 

年代: 1970

 

DOI:10.1122/1.549192

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

The non‐Newtonian melt viscosity‐shear rate relationships of a number of fractions and blends of fractions of ethylene‐propylene‐diene polymers was determined using the Instron Capillary Rheometer. The effect of molecular weight, molecular weight distribution, and temperature of measurements was examined in view of the theoretical derivations by Bueche, and Middleman. The present results could not be correlated by Bueche's expression. The effect of polymer molecular weight distribution given by Middleman was modified by the introduction of chain entanglement. The non‐Newtonian behavior of polymer blends was calculated using the modified equation from the behaviors of individual components. Reasonable agreements were obtained on comparison with experimental results. Empirical relationships for the shear dependence of melt viscosity were derived for the ethylene‐propylene‐diene polymer system. The non‐Newtonian melt viscosity (η)‐shear stress(τw)relationship was correlated by the equation:Log ηη0=−Kτwover the range of shear stress from106to2.5×106 dynes/cm2.The parameter,η0,increased with molecular weight and decreased with temperature; whereas the parameter,K, increased with the breadth of the molecular weight distribution over the range ofMw/Mn=1–20.Samples of very broad molecular weight distributions gave anomolous results. The viscosity at a given shear stress of the polymer fractions is proportional toM̄vbwith the exponentbessentially constant(b=3.6)over the range of shear stress studied.

 

点击下载:  PDF (1013KB)



返 回