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The conversion of 7-acetoxyroyleanone to 14-methoxytaxodione

 

作者: Anne-Marie Faucher,   Robert H. Burnell,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1989）
卷期: Volume 67, issue 1  

页码: 1-4

 

ISSN:0008-4042

 

年代: 1989

 

DOI:10.1139/v89-001

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

7-Acetoxyroyleanone (1a) has been converted in five steps to the methoxy-p-quinone9. Since the latter was the penultimate intermediate in Eugster's partial synthesis of 14-methoxytaxodione (2), the transformation reported represents a formal synthesis of the latter.Keywords: 7-acetoxyroyleanone, 14-methoxytaxodione, synthesis.

 

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