Influence of the Ca:Pb ratio on the superconducting properties of Bi‐based ceramics of type 2223
作者:
T. Rentschler,
C. Schulz,
P. Zoller,
S. Lösch,
E. Raff,
W. Wischert,
S. Kemmler‐Sack,
P. Kessler,
H. Lichte,
T. Nissel,
R. P. Huebener,
期刊:
Annalen der Physik
(WILEY Available online 1994)
卷期:
Volume 506,
issue 2
页码: 71-76
ISSN:0003-3804
年代: 1994
DOI:10.1002/andp.19945060202
出版商: WILEY‐VCH Verlag
关键词: Superconductivity;Bi cuprates;Magnetic properties
数据来源: WILEY
摘要:
AbstractFrom a study of the influence of the Ca: Pb ratio on the superconducting properties of Bibased ceramics of 2223 type it follows that as a second parameter the employed gas atmosphere must be taken into consideration. In case of air preparation good intragrain and intergrain properties are obtained for Ca rich samples (e.g. Bi1.8Pb0.2Sr1.9Ca2.1Cu3Oz); whereas for Pb rich materials (e.g. Bi1.7Pb0.5Sr1.9Ca1.9Cu3Oz) improved conditions are encountered by employment of an Ar/O2(8%) atmosphere during synthesis. Independently, the transition temperature is situated near 108 K.
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