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Conformational transitions of a semiflexible polymer in a liquid crystalline phase

 

作者: Akihiko Matsuyama,  

 

期刊: AIP Conference Proceedings  (AIP Available online 1904)
卷期: Volume 708, issue 1  

页码: 128-129

 

ISSN:0094-243X

 

年代: 1904

 

DOI:10.1063/1.1764087

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Conformations of a single semiflexible polymer chain dissolved in a low molecular weight liquid crystalline solvent (nematogen) are examined by using a mean field theory. We takes into account a stiffness and partial orientational ordering of the polymer. As a result of an anisotropic coupling between the polymer and nematogen, we predict a discontinuous (or continuous) phase transition from a condensed‐rodlike conformation to a swollen‐one of the polymer chain, depending on the stiffness of the polymer. We also study a single polymer chain confined in a smectic phase. © 2004 American Institute of Physics

 

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