High Temperature Proton Exchange Reactions by Hydroxide In Water
作者:
DeanA. Smith,
DonaldR. Dlmmel,
期刊:
Journal of Wood Chemistry and Technology
(Taylor Available online 1984)
卷期:
Volume 4,
issue 1
页码: 75-90
ISSN:0277-3813
年代: 1984
DOI:10.1080/02773818408062284
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The ability of hydroxide Ion to produce carbanlons at 170°C In water has been determined by measuring the extent of deuteratlon and reexchange of deuterium labels for several organic acids and phenols. The results of the exchange reactions provide a rough estimate of the types of reactions that are possible between hydroxide Ion and wood components during alkaline pulping. It has been estimated that NaOH/H20 at 170° can deprotonate organic acids having pKavalues of about 35 and can produce polyanlon intermediates. Several experiments were directed toward understanding the effects of ct-hydroxyl groups and zinc ions on carbanion formation. Exchange reactions involving Na2S at 170° showed that this species is largely dissociated to NaOH and NaSH and that the latter does not contribute to the basicity of the solution.
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