首页   按字顺浏览 期刊浏览 卷期浏览 High Temperature Proton Exchange Reactions by Hydroxide In Water
High Temperature Proton Exchange Reactions by Hydroxide In Water

 

作者: DeanA. Smith,   DonaldR. Dlmmel,  

 

期刊: Journal of Wood Chemistry and Technology  (Taylor Available online 1984)
卷期: Volume 4, issue 1  

页码: 75-90

 

ISSN:0277-3813

 

年代: 1984

 

DOI:10.1080/02773818408062284

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The ability of hydroxide Ion to produce carbanlons at 170°C In water has been determined by measuring the extent of deuteratlon and reexchange of deuterium labels for several organic acids and phenols. The results of the exchange reactions provide a rough estimate of the types of reactions that are possible between hydroxide Ion and wood components during alkaline pulping. It has been estimated that NaOH/H20 at 170° can deprotonate organic acids having pKavalues of about 35 and can produce polyanlon intermediates. Several experiments were directed toward understanding the effects of ct-hydroxyl groups and zinc ions on carbanion formation. Exchange reactions involving Na2S at 170° showed that this species is largely dissociated to NaOH and NaSH and that the latter does not contribute to the basicity of the solution.

 

点击下载:  PDF (513KB)



返 回