Some Factors Affecting the Photosensitized Polymerization of Methyl Methacrylate
作者:
Zhu-Ten Li,
Hitoshi Kubota,
Yoshitaka Ogiwara,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1982)
卷期:
Volume 18,
issue 4
页码: 493-501
ISSN:0022-233X
年代: 1982
DOI:10.1080/00222338208082062
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The effects of sensitizer, alcohol, and reaction temperature on the photosensitized polymerization of methyl methacrylate in cyclohexane-alcohol mixtures were investigated. A maximum conversion was indicated at a certain concentration of alcohol in the mixture for the systems sensitized with quinones such as anthraquinone, 2-tert-butylanthraquinone, and α-naphthoquinone, while it was not observed for the benzophenone-sensitized system. The concentration of alcohol corresponding to the maximum conversion increased in the order methanol < ethanol < n-propanol < n-butanol, and shifted to the lower side by raising the reaction temperature from 20 to 40°C. Based on the absorption and ESR spectra of irradiated solution of quinones, reasons for maximum conversion at an optimum concentration of alcohol are discussed.
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