Equilibrium solubility and permeability of sulfur dioxide in epoxy resin of aliphatic diglycidyl ether
作者:
G. R. Ranade,
V. M. Nadgir,
C. A. Plank,
W. L. S. Laukhuf,
期刊:
Polymer Engineering&Science
(WILEY Available online 1983)
卷期:
Volume 23,
issue 1
页码: 6-12
ISSN:0032-3888
年代: 1983
DOI:10.1002/pen.760230103
出版商: Society of Plastics Engineers, Inc.
数据来源: WILEY
摘要:
AbstractEquilibrium sorption isotherms were obtained for the sulfur dioxide‐epoxy resin of aliphatic diglycidyl ether system over a temperature range of 1° to 45°C. The sorption isotherms indicated the presence of Langmuir sorption due to specific interaction. This is uncommon for rubbery polymers, though similar behavior was also observed previously. Zimm‐Lundberg's clustering analysis indicated a slight tendency for clustering of the penetrant molecules at low temperatures and higher activities. The number of Langmuir sites for sorption was found to be independent of temperature. The mobilities of the molecules sorbed in Henry's law mode and the Langmuir mode were found to be approximately equal. Predictions of the permeability values for this system are presented and compared with other data from the literature. The temperature dependence of different sorption parameters is presented and discussed in d
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