首页   按字顺浏览 期刊浏览 卷期浏览 On the Theory of Radiationless Electronic Transitions. II. The Morse Oscillator Model f...
On the Theory of Radiationless Electronic Transitions. II. The Morse Oscillator Model for Arbitrary Values of the Parameter Z

 

作者: B.I. Makshantsev,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1972)
卷期: Volume 5, issue 1-2  

页码: 7-12

 

ISSN:0038-7010

 

年代: 1972

 

DOI:10.1080/00387017208064678

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

In a previous paper1it has been shown that the harmonic oscillator model is incapable of providing sufficiently large Franck-Condon factors F(E) if realistic parameter values are to be used. In consequence the calculated rate constants v=i/τ of radiationless electronic transitions at E ∼ 3 ev do not agree with those obtained experimentally. It has further been shown that this problem can be solved by using the Morse oscillator model. The calculations, however, were confined to a specific, though frequently encountered, case of the general expression for the Franck-Condon factor of a Morse oscillator, viz., the case of a small parameter =, where δω1-ω, ω1and ω being vibrational frequencies in a higher and lower electronic states respectively, Δr = rei- reis the difference of coordinates of oscillator equilibrium positions in the respective electronic states mentioned, and α is a parameter of the Morse curvefor the lower electronic state.

 

点击下载:  PDF (235KB)



返 回