AbstractBis‐citrato1a‐d, bis‐citramalato2and bis‐malato3germanate(IV) complexes were synthesized from germanium dioxide and citric acid, citramalic acid and malic acid respectively and were identified with IR, NMR and elementary analysis. Crystal 1a is triclinic, space group P1 with a = 7.919(2), b = 7.968(3), c = 9.605(3) Å, α = 94.25(3), β = 108.03(2), γ= 113.05(3)°, Z = 1, and the final residue, R(F), is 0.033 for 2583 reflections. Crystal 2 is monoclinic, space group C2 with a = 10.226(4), b = 12.802(4), c = 6.141(1) Å, β = 100.75(2)°, Z = 2, and the final residue, R(F), is 0.034 for 934 reflections. Both1aand2have slightly distorted octahedral structures with citrate or citramalate ions as a tridentate ligand that forms five‐, six‐ and seven‐membered rings with the central metal. There is a two‐fold axis through the central atom of compound2instead of the inversion center of1a. Same structures for these six complexes are indicated because the spectral patterns of the other four compounds,1b‐dand3, are similar to