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Thermodynamic Properties of the NaBr+H2O System

 

作者: Donald G. Archer,  

 

期刊: Journal of Physical & Chemical Reference Data  (AIP Available online 1991)
卷期: Volume 20, issue 3  

页码: 509-555

 

ISSN:0047-2689

 

年代: 1991

 

DOI:10.1063/1.555888

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Equations that described the thermodynamic properties of the NaBr+H2O system were obtained from a fit to experimental results for this system. The experimental results included in the fit spanned the range of temperature of approximately 260 to 623 K and the range of pressure from the vapor pressure of the solution to 150 MPa. New equations and/or values for the following properties are given in the present work: 1) the change in chemical potential with respect to temperature and pressure for NaBr(cr), valid from 200 to 900 K, 2) &Dgr;fG0mand &Dgr;fH0mfor formation from the elements for NaBr(cr) for 298.15 K and 0.1 MPa, 3) &Dgr;fG0mand &Dgr;fH0mfrom the elements, as well asS0mandC0p,m, all for 298.15 K, 0.1 MPa for NaBr⋅2H2O(cr), 4) the change in chemical potential for both NaBr and H2O in NaBr(aq) as a function of temperature, pressure, and molality, valid from 260 to 600 K and from the vapor pressure of the solution to 150 MPa.

 

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