A Novel Approach to Theories of Polymer Coils in Good Solvents
作者:
TejrajM. Aminabhavi,
RamachandraH. Balundgi,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1986)
卷期:
Volume 23,
issue 1
页码: 77-86
ISSN:0022-233X
年代: 1986
DOI:10.1080/00222338608063376
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A new theory is proposed involving a short-range interaction parameter, N0, which allows for finite chain effects. The parameter z, which was originally suggested by Yamakawa, is redefined to make it applicable to finite chains. The dependence of intrinsic viscosity on molecular mass as predicted by most of the acknowledged theories of polymer solution seem to be incompatible with the Mark-Houwink-Sakurada relation. This makes the evaluation of interaction parameters from viscosity data difficult. Therefore, an attempt is made here to show that these theories contain some basic assumptions (and/or mathematical simplifications) which may lead to erroneous conclusions.
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