Electrochemical Studies of Iron(II) 4,4′,4″, 4′″-Tetrasulfophthalocyanine
作者:
Chia-Yu Li,
Der-Hang Chin,
期刊:
Analytical Letters
(Taylor Available online 1975)
卷期:
Volume 8,
issue 5
页码: 291-299
ISSN:0003-2719
年代: 1975
DOI:10.1080/00032717508058211
出版商: Taylor & Francis Group
关键词: iron (11) 4,4′,4″,4′″-tetrasulfophthalocyanine;polarography;spectroscopy
数据来源: Taylor
摘要:
Electrochemical reductions of iron(II) 4,4′,4″,4′″-tetrasulfophthalocyanine (Fe(II)TSP) in dimethyl sulfoxide (DMSO) on a mercury electrode have been examined. The iron compound was found to undergo two one-electron reductions (at -0.74 and -1.15 V vs. SCE respectively) to Fe(0) as verified by polarographic measurements. The course of reduction was followed by observing the spectral change in a combined optical-electrochemical cell. The influence of such extraplanar ligands as cyanide, pyridine, and imidazole, etc., on the half-wave potentials were also noted.
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