Kinetic Modeling of Carbon Suboxide Thermal Decomposition and Formation of Soot-Like Particles Behind Shock Waves
作者:
J. SOJKA,
J. WARNATZ,
P.A. VLASOV,
I.S. ZASLONKO,
期刊:
Combustion Science and Technology
(Taylor Available online 2000)
卷期:
Volume 158,
issue 1
页码: 439-460
ISSN:0010-2202
年代: 2000
DOI:10.1080/00102200008947344
出版商: Taylor & Francis Group
关键词: carbon suboxide;carbon cluster;kinetic modeling;soot formation
数据来源: Taylor
摘要:
The kinetic modeling of thermal decomposition of C3O2and formation of soot-like solid particles behind shock waves is carried out. The transformation of C atoms up to the cluster C30in the gas phase and the formation, growth, transfer, and coagulation of carbon solid particles are modeled with the help of a detailed gas phase kinetic scheme combined with a discrete Galerkin method. Together with the calculation of concentration profiles of small carbon clusters, precursors of solid panicles, soot-like solid particles, and fullerene-like solid particles, the temperature dependencies on the induction period, the growth rate constant, the yield, and the mean size of carbon solid particles are obtained for a mixture of 0.33 % C3O2in argon for the following experimental conditions: A pressure of 5.0 MPa and a temperature range of 1200 to 2250 K. The comparison of these calculated values with the experimentally measured ones is performed and the possible pathways of transformation of C atoms from C3O2to soot-like solid particles are analyzed.
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