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Pyrrole Chemistry. Part XI. Some Reactions of the Pyrrole Grignard Reagent with Alkyl Carbonates and Alkyl Thiocarbonates

 

作者: C. E. Loader,   Hugh J. Anderson,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1971）
卷期: Volume 49, issue 1  

页码: 45-48

 

ISSN:0008-4042

 

年代: 1971

 

DOI:10.1139/v71-007

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

The pyrrole Grignard reagent reacts with ethyl thiocarbonates to give good yields of ethyl 2-pyrrole-thiocarboxylates.Diethyl carbonate, by contrast, in accordance with earlier reports gives almost exclusively ethyl 1-pyrrolecarboxylate.2-Pyrrolecarbonitrile was prepared in good yield from the pyrrole Grignard reagent and ethyl thiocyanate.

 

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