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Electric field effect on the nematic-isotropic phase transition

 

作者: E.I. Rjumtse,   M.A. Osipov,   T.A. Rotinyan,   N.P. Yevlampieva,  

 

期刊: Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 18, issue 1  

页码: 87-95

 

ISSN:0267-8292

 

年代: 1995

 

DOI:10.1080/02678299508036595

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Pulsed electric fields are used to study the influence of a strong field on the nematic-isotropic phase transition for cyanobiphenyl and stilbene-type liquid crystals. Deviation of the electric field-induced optical anisotropy from the Kerr law is observed and it is shown that such electric fields can shift the transition temperature substantially. The induced birefringence and the shift of the transition temperature are measured as a function of the electric field strength. The results are explained qualitatively in the context of the Landau-De Gennes theory with two order parameters. The coefficients of the phenomenological theory are calculated using the simple density functional theory of polar nematics developed in this paper and the results for the shift of the transition temperature are compared with experiment results.

 

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