HMO theory and cyclophosphazenes
作者:
N.L. Paddock,
期刊:
International Reviews in Physical Chemistry
(Taylor Available online 1986)
卷期:
Volume 5,
issue 2-3
页码: 161-168
ISSN:0144-235X
年代: 1986
DOI:10.1080/01442358609353378
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Hückel molecular orbital (HMO) theory is applied to (1) the bond lengths in phosphazenes arising from inhomogeneous substitution or complex formation, (2) conjugation between exocyclic groups and the ring and its consequences, and (3) chemical reactivity, carbanion stabilization and molecular rearrangements. Such bond characteristics as order, polarizability and electron localizability depend differently on relative orbital electronegativity. Ring size effects distinguish interactions of different symmetry types. Necessary theoretical improvements are briefly considered.
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