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Squeezing Flow of Highly Viscous Polymers

 

作者: M. A. McClelland,   B. A. Finlayson,  

 

期刊: Journal of Rheology  (AIP Available online 1988)
卷期: Volume 32, issue 2  

页码: 101-133

 

ISSN:0148-6055

 

年代: 1988

 

DOI:10.1122/1.549993

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

Experimental results are reported for the constant‐force squeezing of three highly viscous polymers. Profiles for the plate separation versus time were measured with the use of a modified materials testing system. Two polybutenes were tested at 25 °C, and a low‐density polyethylene melt (IUPAC sample X) was studied at 150 °C. Measured half‐times show that the polybutenes behave as inelastic fluids with viscosities that decrease slightly with shear rate. In slow squeezes the experimental results agree with the predictions of Newtonian fluid theory corresponding to the available viscosity measurements. The behavior of LDPE X is described by the CEF model in both slow and fast squeezes. Although shear rates are as high as1000 s−1,the elastic effects for LDPE X are small compared to viscous effects.

 

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