Out‐of‐plane orientational dynamics of polymer liquid crystals under flow
作者:
N. C. Andrews,
A. J. McHugh,
B. J. Edwards,
期刊:
Journal of Rheology
(AIP Available online 1996)
卷期:
Volume 40,
issue 3
页码: 459-469
ISSN:0148-6055
年代: 1996
DOI:10.1122/1.550754
出版商: The Society of Rheology
关键词: Liquid crystal polymers;Orientation, liquid‐crystalline polymer;Hamiltonian formulation;Tumbling;LIQUID CRYSTALS;POLYMERS;ORIENTATION;HAMILTONIAN FUNCTION;MAGNETIC FIELDS;TRANSIENTS
数据来源: AIP
摘要:
The nonplanar orientational dynamics of polymer liquid crystals is investigated using a continuum theory based on Hamiltonian mechanics. The initial out‐of‐plane orientation is generated through the application of a magnetic field which naturally appears in the Hamiltonian of the system. Our analysis begins at the instant the magnetic field is turned off and the flow is started. It is found that the orientational pattern is varied and rich in transitions. The ‘‘kayaking’’ states and the shear‐plane tumbling states are found to be the dominant attractors for the majority of the parameter space. Also, this theory has an inbuiltnonaffineparameter which is found to have an important effect on the nature of the final stable orientations.
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