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Out‐of‐plane orientational dynamics of polymer liquid crystals under flow

 

作者: N. C. Andrews,   A. J. McHugh,   B. J. Edwards,  

 

期刊: Journal of Rheology  (AIP Available online 1996)
卷期: Volume 40, issue 3  

页码: 459-469

 

ISSN:0148-6055

 

年代: 1996

 

DOI:10.1122/1.550754

 

出版商: The Society of Rheology

 

关键词: Liquid crystal polymers;Orientation, liquid‐crystalline polymer;Hamiltonian formulation;Tumbling;LIQUID CRYSTALS;POLYMERS;ORIENTATION;HAMILTONIAN FUNCTION;MAGNETIC FIELDS;TRANSIENTS

 

数据来源: AIP

 

摘要:

The nonplanar orientational dynamics of polymer liquid crystals is investigated using a continuum theory based on Hamiltonian mechanics. The initial out‐of‐plane orientation is generated through the application of a magnetic field which naturally appears in the Hamiltonian of the system. Our analysis begins at the instant the magnetic field is turned off and the flow is started. It is found that the orientational pattern is varied and rich in transitions. The ‘‘kayaking’’ states and the shear‐plane tumbling states are found to be the dominant attractors for the majority of the parameter space. Also, this theory has an inbuiltnonaffineparameter which is found to have an important effect on the nature of the final stable orientations.

 

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