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Orientational Order in Simple Polar Liquids: Effect of the Quadrupole Moment

 

作者: Dongqing Wei,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1995)
卷期: Volume 269, issue 1  

页码: 89-98

 

ISSN:1058-725X

 

年代: 1995

 

DOI:10.1080/10587259508037323

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Molecular dynamics (MD) simulations were carried out to investigate the effect of the quadrupole moment on the orientational order in polar liquids. A simple model of soft sphere with a point dipole and a linear quadrupole was employed in the current study. It is found that the quadrupole moment shifts the isotropic to ferroelectric nematic and the ferroelectric nematic to solid phase transitions to higher density. The columnar order appears at much lower temperature as compared with the pure dipole liquid.

 

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