AQUEOUS TWO PHASE SYSTEMS FROM CYCLODEXTRIN POLYMERS AND HYDROPHOBICALLY MODIFIED ACRYLIC POLYMERS
作者:
N.M. Gosselet,
C. Borie,
C. Amiel,
B. Sebille,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1998)
卷期:
Volume 19,
issue 6-7
页码: 805-820
ISSN:0193-2691
年代: 1998
DOI:10.1080/01932699808913216
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In this study, a copolymer of N,N-dimethylacrylamide and hydroxyethyl-methacrylate was synthesized and hydrophobically modified with about 2 mole % of adamantyl groups. The mixing of this modified copolymer with water-soluble β-cyclodextrin polymers reveals thickening properties. Inclusion complexes formation between adamantyl groups and β-cyclodextrin cavities are responsible of intermolecular associations. Above a given total polymer concentration a phase separation occurs, giving a gel phase topped by a liquid phase. We have stated the phase diagram by analysis of the two phases in equilibrium. It has been observed that the two polymers are present in both phases and that the gel phase is more concentrated than the other one. This phase behavior is an original complex coacervation phenomenom which is due to the specific attractive interactions of the two different macromolecules: inclusion complexes formed between the two neutral polymers.
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