Infrared spectra of the new molecular complex C60·2[(C6H5)3P]AuCl·0.1 C6H5CH3
作者:
S. Król,
A. Łapiński,
A. Graja,
期刊:
Advanced Materials for Optics and Electronics
(WILEY Available online 1996)
卷期:
Volume 6,
issue 5‐6
页码: 255-260
ISSN:1057-9257
年代: 1996
DOI:10.1002/(SICI)1099-0712(199609)6:5/6<255::AID-AMO268>3.0.CO;2-D
出版商: John Wiley&Sons Ltd.
关键词: fullerene;C60complex;IR spectra;temperature dependences;intermolecular interactions;specific interactions
数据来源: WILEY
摘要:
AbstractWe report on the wealth of IR spectra of single crystals of the C60complex with chloro(triphenylphosphine)gold grown from toluene solution. The spectra are strongly temperature‐dependent at about 200 K. The dependence of the spectral parameters is attributed to variations in the molecular dynamics of the C60molecules and changes in the interactions between the fullerene and donor/solvent molecules. Some general considerations on the origin of the IR spectral variation vs. temperature are also presente
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